| Round | Date / Time | Match | Score |
|---|---|---|---|
| 1 | 07 Sep 2022 21:00 | Napoli - Liverpool | 4:1 |
| 2 | 14 Sep 2022 21:00 | Rangers - Napoli | 0:3 |
| 3 | 04 Oct 2022 21:00 | Ajax - Napoli | 1:6 |
| 4 | 12 Oct 2022 18:45 | Napoli - Ajax | 4:2 |
| 5 | 26 Oct 2022 21:00 | Napoli - Rangers | 3:0 |
| 6 | 01 Nov 2022 21:00 | Liverpool - Napoli | 2:0 |
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