| Round | Date / Time | Match | Score |
|---|---|---|---|
| 1 | 07 Sep 2022 21:00 | Napoli - Liverpool | 4:1 |
| 2 | 13 Sep 2022 21:00 | Liverpool - Ajax | 2:1 |
| 3 | 04 Oct 2022 21:00 | Liverpool - Rangers | 2:0 |
| 4 | 12 Oct 2022 21:00 | Rangers - Liverpool | 1:7 |
| 5 | 26 Oct 2022 21:00 | Ajax - Liverpool | 0:3 |
| 6 | 01 Nov 2022 21:00 | Liverpool - Napoli | 2:0 |
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