| Round | Date / Time | Match | Score |
|---|---|---|---|
| 1 | 17 Sep 2024 18:45 | Juventus - PSV Eindhoven | 3:1 |
| 2 | 01 Oct 2024 21:00 | PSV Eindhoven - Sporting | |
| 3 | 22 Oct 2024 21:00 | Paris Saint-Germain - PSV Eindhoven | |
| 4 | 05 Nov 2024 18:45 | PSV Eindhoven - Girona FC | |
| 5 | 27 Nov 2024 21:00 | PSV Eindhoven - Shakhtar Donetsk | |
| 6 | 10 Dec 2024 21:00 | Stade Brestois - PSV Eindhoven | |
| 7 | 21 Jan 2025 21:00 | FK Crvena zvezda - PSV Eindhoven | |
| 8 | 29 Jan 2025 21:00 | PSV Eindhoven - Liverpool |
| Pos | Team | G | W | D | L | Pts | |
| 1 | FC Bayern München | 1 | 1 | 0 | 0 | 3 | |
| 2 | Celtic | 1 | 1 | 0 | 0 | 3 | |
| 3 | Bayer 04 Leverkusen | 1 | 1 | 0 | 0 | 3 | |
| 4 | Sparta Praha | 1 | 1 | 0 | 0 | 3 | |
| 5 | Borussia Dortmund | 1 | 1 | 0 | 0 | 3 | |
| 6 | Aston Villa | 1 | 1 | 0 | 0 | 3 | |
| 7 | Real Madrid | 1 | 1 | 0 | 0 | 3 | |
| 8 | Juventus | 1 | 1 | 0 | 0 | 3 | |
| 9 | Liverpool | 1 | 1 | 0 | 0 | 3 | |
| 10 | Sporting | 1 | 1 | 0 | 0 | 3 | |
| 11 | AS Monaco | 1 | 1 | 0 | 0 | 3 | |
| 12 | Benfica | 1 | 1 | 0 | 0 | 3 | |
| 13 | Atlético Madrid | 1 | 1 | 0 | 0 | 3 | |
| 14 | Stade Brestois | 1 | 1 | 0 | 0 | 3 | |
| 15 | Paris Saint-Germain | 1 | 1 | 0 | 0 | 3 | |
| 16 | Shakhtar Donetsk | 1 | 0 | 1 | 0 | 1 | |
| 17 | Manchester City | 1 | 0 | 1 | 0 | 1 | |
| 18 | Arsenal | 1 | 0 | 1 | 0 | 1 | |
| 19 | Atalanta | 1 | 0 | 1 | 0 | 1 | |
| 20 | Inter | 1 | 0 | 1 | 0 | 1 | |
| 21 | Bologna | 1 | 0 | 1 | 0 | 1 | |
| 22 | Barcelona | 1 | 0 | 0 | 1 | 0 | |
| 23 | FK Crvena zvezda | 1 | 0 | 0 | 1 | 0 | |
| 24 | RB Leipzig | 1 | 0 | 0 | 1 | 0 | |
| 25 | SK Sturm Graz | 1 | 0 | 0 | 1 | 0 | |
| 26 | Girona FC | 1 | 0 | 0 | 1 | 0 | |
| 27 | Milan | 1 | 0 | 0 | 1 | 0 | |
| 28 | PSV Eindhoven | 1 | 0 | 0 | 1 | 0 | |
| 29 | VfB Stuttgart | 1 | 0 | 0 | 1 | 0 | |
| 30 | Lille | 1 | 0 | 0 | 1 | 0 | |
| 31 | Young Boys | 1 | 0 | 0 | 1 | 0 | |
| 32 | Red Bull Salzburg | 1 | 0 | 0 | 1 | 0 | |
| 33 | Club Brugge KV | 1 | 0 | 0 | 1 | 0 | |
| 34 | ŠK Slovan Bratislava | 1 | 0 | 0 | 1 | 0 | |
| 35 | Feyenoord | 1 | 0 | 0 | 1 | 0 | |
| 36 | GNK Dinamo Zagreb | 1 | 0 | 0 | 1 | 0 | |
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