| Date | Time | Host | Scr | Guest | |
| 06 Apr 2021 21:00 | Manchester City | 2 : 1 | Borussia Dortmund | |
| 06 Apr 2021 21:00 | Real Madrid | 3 : 1 | Liverpool | |
| 07 Apr 2021 21:00 | Porto | 0 : 2 | Chelsea | |
| 07 Apr 2021 21:00 | Bayern Munich | 2 : 3 | PSG | |
| 14 Apr 2021 21:00 | Borussia Dortmund | : | Manchester City | |
| 14 Apr 2021 21:00 | Liverpool | : | Real Madrid | |
| 13 Apr 2021 21:00 | Chelsea | : | Porto | |
| 13 Apr 2021 21:00 | PSG | : | Bayern Munich |
| Date | Time | Host | Scr | Guest | |
| 16 Feb 2021 21:00 | Barcelona | 1 : 4 | PSG | |
| 16 Feb 2021 21:00 | RB Leipzig | 0 : 2 | Liverpool | |
| 17 Feb 2021 21:00 | Porto | 2 : 1 | Juventus | |
| 17 Feb 2021 21:00 | Sevilla | 2 : 3 | Borussia Dortmund | |
| 23 Feb 2021 21:00 | Atlético Madrid | 0 : 1 | Chelsea | |
| 23 Feb 2021 21:00 | Lazio | 1 : 4 | Bayern Munich | |
| 24 Feb 2021 21:00 | Atalanta | 0 : 1 | Real Madrid | |
| 24 Feb 2021 21:00 | Borussia M'gladbach | 0 : 2 | Manchester City | |
| 09 Mar 2021 21:00 | Juventus | 3 : 2 | Porto | |
| 09 Mar 2021 21:00 | Borussia Dortmund | 2 : 2 | Sevilla | |
| 10 Mar 2021 21:00 | Liverpool | 2 : 0 | RB Leipzig | |
| 10 Mar 2021 21:00 | PSG | 1 : 1 | Barcelona | |
| 16 Mar 2021 21:00 | Manchester City | 2 : 0 | Borussia M'gladbach | |
| 16 Mar 2021 21:00 | Real Madrid | 3 : 1 | Atalanta | |
| 17 Mar 2021 21:00 | Chelsea | 2 : 0 | Atlético Madrid | |
| 17 Mar 2021 21:00 | Bayern Munich | 2 : 1 | Lazio |
| Date | Time | Host | Scr | Guest | |
| 08 Apr 2021 21:00 | Granada | 0 : 2 | Manchester United | |
| 08 Apr 2021 21:00 | Arsenal | 1 : 1 | Slavia Praha | |
| 08 Apr 2021 21:00 | Ajax | 1 : 2 | Roma | |
| 08 Apr 2021 21:00 | Dinamo Zagreb | 0 : 1 | Villarreal | |
| 15 Apr 2021 21:00 | Manchester United | : | Granada | |
| 15 Apr 2021 21:00 | Slavia Praha | : | Arsenal | |
| 15 Apr 2021 21:00 | Roma | : | Ajax | |
| 15 Apr 2021 21:00 | Villarreal | : | Dinamo Zagreb |
| 18 Oct 2020 15:00 | Angers SCO | 1 : 1 | Metz | |
| 16 Oct 2020 19:00 | Dijon | 1 : 1 | Rennes | |
| 18 Oct 2020 21:00 | Lille | 4 : 0 | Lens | |
| 17 Oct 2020 21:00 | Olympique Marseille | 3 : 1 | Bordeaux | |
| 18 Oct 2020 15:00 | Monaco | 1 : 1 | Montpellier | |
| 18 Oct 2020 15:00 | Nantes | 3 : 1 | Brest | |
| 16 Oct 2020 21:00 | Nîmes | 0 : 4 | PSG | |
| 17 Oct 2020 17:00 | Reims | 1 : 3 | Lorient | |
| 18 Oct 2020 17:00 | Saint-Etienne | 1 : 3 | Nice | |
| 18 Oct 2020 13:00 | Strasbourg | 2 : 3 | Olympique Lyonnais |
| 18 Apr 2021 15:30 | Borussia Dortmund | : | Werder | |
| 16 Apr 2021 20:30 | RB Leipzig | : | Hoffenheim | |
| 17 Apr 2021 15:30 | Borussia M'gladbach | : | Eintracht Frankfurt | |
| 17 Apr 2021 18:30 | Bayer 04 | : | Köln | |
| 17 Apr 2021 15:30 | Wolfsburg | : | Bayern | |
| 17 Apr 2021 15:30 | Freiburg | : | Schalke 04 | |
| 17 Apr 2021 15:30 | Union Berlin | : | Stuttgart | |
| 18 Apr 2021 18:00 | Mainz 05 | : | Hertha BSC | |
| 17 Apr 2021 15:30 | Augsburg | : | Arminia |
| 18 Apr 2021 14:30 | Arsenal | : | Fulham | |
| 21 Apr 2021 21:15 | Aston Villa | : | Manchester City | |
| 20 Apr 2021 21:00 | Chelsea | : | Brighton | |
| 16 Apr 2021 21:00 | Everton | : | Tottenham Hotspur | |
| 19 Apr 2021 21:00 | Leeds United | : | Liverpool | |
| 22 Apr 2021 21:00 | Leicester City | : | West Bromwich Albion | |
| 18 Apr 2021 17:00 | Manchester United | : | Burnley | |
| 17 Apr 2021 13:30 | Newcastle United | : | West Ham United | |
| 17 Apr 2021 00:00 | Southampton | : | Crystal Palace | |
| 17 Apr 2021 16:00 | Wolverhampton | : | Sheffield United |
| 21 Apr 2021 00:00 | Deportivo Alavés | : | Villarreal | |
| 21 Apr 2021 00:00 | Atletico Madrid | : | Huesca | |
| 21 Apr 2021 00:00 | Barcelona | : | Getafe | |
| 21 Apr 2021 00:00 | Real Betis | : | Athletic Club | |
| 21 Apr 2021 00:00 | Cádiz | : | Real Madrid | |
| 21 Apr 2021 00:00 | Granada | : | Eibar | |
| 21 Apr 2021 00:00 | Levante | : | Sevilla | |
| 21 Apr 2021 00:00 | Osasuna | : | Valencia | |
| 21 Apr 2021 00:00 | Real Sociedad | : | Celta Vigo | |
| 21 Apr 2021 00:00 | Elche | : | Real Valladolid |
| 18 Apr 2021 15:00 | Lazio | : | Benevento | |
| 17 Apr 2021 18:00 | Sassuolo | : | Fiorentina | |
| 18 Apr 2021 12:30 | Milan | : | Genoa | |
| 18 Apr 2021 20:45 | Napoli | : | Internazionale | |
| 18 Apr 2021 15:00 | Atalanta | : | Juventus | |
| 17 Apr 2021 20:45 | Cagliari | : | Parma | |
| 18 Apr 2021 18:00 | Torino | : | Roma | |
| 18 Apr 2021 15:00 | Bologna | : | Spezia | |
| 17 Apr 2021 15:00 | Crotone | : | Udinese | |
| 17 Apr 2021 15:00 | Sampdoria | : | Hellas Verona |
| 11 Apr 2021 00:00 | Rostov | : | Rubin Kazan | |
| 11 Apr 2021 00:00 | CSKA Moscow | : | Rotor Volgograd | |
| 11 Apr 2021 00:00 | Dinamo Moscow | : | Ural | |
| 11 Apr 2021 00:00 | Lokomotiv Moscow | : | Spartak Moscow | |
| 11 Apr 2021 00:00 | Sochi | : | Zenit | |
| 11 Apr 2021 00:00 | Arsenal Tula | : | Krasnodar | |
| 11 Apr 2021 00:00 | Ufa | : | Akhmat Grozny | |
| 11 Apr 2021 00:00 | Khimki | : | Tambov |
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