| 10 Apr 2021 21:00 | Montpellier | : | Olympique Marseille | |
| 10 Apr 2021 17:00 | Strasbourg | : | PSG |
| 10 Apr 2021 15:30 | Bayern | : | Union Berlin | |
| 10 Apr 2021 15:30 | Eintracht Frankfurt | : | Wolfsburg | |
| 10 Apr 2021 15:30 | Hertha BSC | : | Borussia M'gladbach | |
| 10 Apr 2021 15:30 | Werder | : | RB Leipzig | |
| 10 Apr 2021 18:30 | Stuttgart | : | Borussia Dortmund |
| 2nd ht | Erzgebirge Aue | 0 : 3 | FC St. Pauli | |
| 10 Apr 2021 13:00 | Fortuna Düsseldorf | : | Karlsruher SC | |
| 10 Apr 2021 13:00 | Holstein Kiel | : | SSV Jahn Regensburg | |
| 2nd ht | SC Paderborn 07 | 2 : 0 | VfL Bochum |
| 10 Apr 2021 18:30 | Crystal Palace | : | Chelsea | |
| 10 Apr 2021 16:00 | Liverpool | : | Aston Villa | |
| 43' | Manchester City | 0 : 1 | Leeds United |
| 10 Apr 2021 16:15 | Athletic Club | : | Deportivo Alavés | |
| 10 Apr 2021 18:30 | Eibar | : | Levante | |
| 10 Apr 2021 14:00 | Getafe | : | Cádiz | |
| 10 Apr 2021 21:00 | Real Madrid | : | Barcelona |
| 10 Apr 2021 15:00 | Spezia | : | Crotone | |
| 10 Apr 2021 18:00 | Parma | : | Milan | |
| 10 Apr 2021 20:45 | Udinese | : | Torino |
| 10 Apr 2021 16:30 | Boavista | : | Rio Ave | |
| 10 Apr 2021 16:00 | Marítimo | : | SC Farense | |
| 10 Apr 2021 21:30 | Paços de Ferreira | : | SL Benfica | |
| 10 Apr 2021 19:00 | Tondela | : | FC Porto |
| 10 Apr 2021 20:00 | AZ Alkmaar | : | Sparta Rotterdam | |
| 10 Apr 2021 20:00 | Fortuna Sittard | : | FC Emmen | |
| 10 Apr 2021 18:45 | Heracles Almelo | : | Willem II Tilburg | |
| 10 Apr 2021 21:00 | PEC Zwolle | : | FC Twente |
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