| 17' | Lorient | 0 : 0 | Olympique Marseille | |
| 24 Oct 2020 21:00 | PSG | : | Dijon |
| 24 Oct 2020 15:30 | Bayern | : | Eintracht Frankfurt | |
| 24 Oct 2020 18:30 | Borussia Dortmund | : | Schalke 04 | |
| 24 Oct 2020 15:30 | RB Leipzig | : | Hertha BSC | |
| 24 Oct 2020 15:30 | Union Berlin | : | Freiburg | |
| 24 Oct 2020 15:30 | Mainz 05 | : | Borussia M'gladbach |
| 59' | Fulham | 0 : 1 | Crystal Palace | |
| 24 Oct 2020 21:00 | Liverpool | : | Sheffield United | |
| 24 Oct 2020 18:30 | Manchester United | : | Chelsea | |
| 24 Oct 2020 13:30 | West Ham United | 1 : 1 | Manchester City |
| 24 Oct 2020 21:00 | Atletico Madrid | : | Real Betis | |
| 58' | Barcelona | 1 : 1 | Real Madrid | |
| 24 Oct 2020 18:30 | Osasuna | : | Athletic Club | |
| 24 Oct 2020 18:30 | Sevilla | : | Eibar |
| 24 Oct 2020 15:00 | Atalanta | : | Sampdoria | |
| 24 Oct 2020 18:00 | Genoa | : | Internazionale | |
| 24 Oct 2020 20:45 | Lazio | : | Bologna |
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