| 14 Feb 2021 15:00 | Angers SCO | 1 : 3 | Nantes | |
| 14 Feb 2021 21:00 | Bordeaux | 0 : 0 | Olympique Marseille | |
| 14 Feb 2021 15:00 | Dijon | 0 : 2 | Nîmes | |
| 14 Feb 2021 17:00 | Lille | 0 : 0 | Brest | |
| 14 Feb 2021 15:00 | Metz | 1 : 2 | Strasbourg | |
| 14 Feb 2021 13:00 | Monaco | 2 : 2 | Lorient | |
| 14 Feb 2021 15:00 | Rennes | 0 : 2 | Saint-Etienne |
| 14 Feb 2021 18:00 | Wolfsburg | 0 : 0 | Borussia M'gladbach | |
| 14 Feb 2021 15:30 | Eintracht Frankfurt | 2 : 0 | Köln |
| 14 Feb 2021 13:30 | 1. FC Nürnberg | 1 : 2 | FC St. Pauli | |
| 14 Feb 2021 13:30 | Darmstadt 98 | 1 : 0 | VfL Osnabrück | |
| 14 Feb 2021 13:30 | VfL Bochum | 2 : 0 | Eintracht Braunschweig |
| 14 Feb 2021 17:30 | Arsenal | 4 : 2 | Leeds United | |
| 14 Feb 2021 20:00 | Everton | 0 : 2 | Fulham | |
| 14 Feb 2021 13:00 | Southampton | 1 : 2 | Wolverhampton | |
| 14 Feb 2021 15:00 | West Bromwich Albion | 1 : 1 | Manchester United |
| 14 Feb 2021 14:00 | Getafe | 0 : 1 | Real Sociedad | |
| 14 Feb 2021 18:30 | Levante | 0 : 1 | Osasuna | |
| 14 Feb 2021 16:15 | Real Madrid | 2 : 0 | Valencia | |
| 14 Feb 2021 21:00 | Villarreal | 1 : 2 | Real Betis |
| 14 Feb 2021 15:00 | Cagliari | 0 : 1 | Atalanta | |
| 14 Feb 2021 15:00 | Sampdoria | 2 : 1 | Fiorentina | |
| 14 Feb 2021 20:45 | Internazionale | 3 : 1 | Lazio | |
| 14 Feb 2021 18:00 | Crotone | 1 : 2 | Sassuolo | |
| 14 Feb 2021 12:30 | Roma | 3 : 0 | Udinese |
| 14 Feb 2021 18:30 | CD Santa Clara | 0 : 1 | Sporting Braga | |
| 14 Feb 2021 21:15 | Moreirense | 1 : 1 | SL Benfica | |
| 14 Feb 2021 16:00 | Portimonense | 4 : 1 | Gil Vicente FC |
| 14 Feb 2021 12:15 | AZ Alkmaar | 3 : 1 | Heerenveen | |
| 14 Feb 2021 14:30 | FC Utrecht | 3 : 1 | VVV-Venlo | |
| 14 Feb 2021 14:30 | Feyenoord | 5 : 0 | Willem II Tilburg | |
| 14 Feb 2021 16:45 | Vitesse | 0 : 2 | FC Twente |
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