| 18 Feb 2021 18:55 | Wolfsberger AC | 1 : 4 | Tottenham Hotspur | |
| 18 Feb 2021 16:00 | Dynamo Kyiv | : | Club Brugge | |
| 18 Feb 2021 18:55 | Real Sociedad | 0 : 4 | Manchester United | |
| 18 Feb 2021 18:55 | Crvena zvezda | 2 : 2 | Milan | |
| 18 Feb 2021 18:55 | Slavia Praha | 0 : 0 | Leicester City | |
| 18 Feb 2021 18:55 | Sporting Braga | 0 : 2 | Roma | |
| 18 Feb 2021 18:55 | Krasnodar | 2 : 3 | Dinamo Zagreb | |
| 18 Feb 2021 18:55 | Young Boys | 4 : 3 | Bayer Leverkusen | |
| 18 Feb 2021 18:55 | Olympiacos | 4 : 2 | PSV | |
| 18 Feb 2021 21:00 | SL Benfica | 1 : 1 | Arsenal | |
| 18 Feb 2021 21:00 | Antwerp | 3 : 4 | Rangers | |
| 18 Feb 2021 21:00 | RB Salzburg | 0 : 2 | Villarreal | |
| 18 Feb 2021 21:00 | Molde | 3 : 3 | Hoffenheim | |
| 18 Feb 2021 21:00 | Granada | 2 : 0 | Napoli | |
| 18 Feb 2021 21:00 | Maccabi Tel Aviv | 0 : 2 | Shakhtar Donetsk | |
| 18 Feb 2021 21:00 | Lille | 1 : 2 | Ajax |
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