| 23 Jan 2021 17:00 | Lens | 0 : 1 | Nice | |
| 23 Jan 2021 21:00 | Monaco | 3 : 1 | Olympique Marseille |
| 23 Jan 2021 15:30 | Bayer 04 | 0 : 1 | Wolfsburg | |
| 23 Jan 2021 15:30 | Freiburg | 2 : 1 | Stuttgart | |
| 23 Jan 2021 18:30 | Hertha BSC | 1 : 4 | Werder | |
| 23 Jan 2021 15:30 | Mainz 05 | 3 : 2 | RB Leipzig | |
| 23 Jan 2021 15:30 | Augsburg | 2 : 1 | Union Berlin | |
| 23 Jan 2021 15:30 | Arminia | 1 : 5 | Eintracht Frankfurt |
| 23 Jan 2021 21:00 | Deportivo Alavés | 1 : 4 | Real Madrid | |
| 23 Jan 2021 14:00 | Huesca | 0 : 0 | Villarreal | |
| 23 Jan 2021 18:30 | Real Sociedad | 2 : 2 | Real Betis | |
| 23 Jan 2021 16:15 | Sevilla | 3 : 0 | Cádiz |
| 23 Jan 2021 20:45 | Fiorentina | 2 : 1 | Crotone | |
| 23 Jan 2021 18:00 | Milan | 0 : 3 | Atalanta | |
| 23 Jan 2021 15:00 | Roma | 4 : 3 | Spezia | |
| 23 Jan 2021 18:00 | Udinese | 0 : 0 | Internazionale |
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